Characterization and 1H-NMR applications of hexaaza macrocyclic complexes of lanthanides

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Title: Characterization and 1H-NMR applications of hexaaza macrocyclic complexes of lanthanides
Author: DiSano, Mary
Abstract: Samples of PrL(CH3C00)2Cl-nH20 ( L=2,7J3,1S,-tetremethyl- 3,6, 1 4, 1 7,23,24-hexaazatricycloi 1 7.3. 1 .18'12] tetracosa-1(23), 2, 6, 8, 10, 12(24), 13, 17, 19, 21-decaene) were tested as lanthanide shift reagents using 1-heptanol, diisopropyl amine and hexylamine as substrates. These tests were unsuccessful. Syntheses of similar compounds with nitrate, carbonate, picrate, and chloroacetate counteranions were attempted in our desire to prepare template complexes with displeceable counteranions. A successful lanthanide shift reagent has not yet been synthesized.
Record URI: http://hdl.handle.net/1850/11433
Date: 1989-07

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