Characterization and 1H-NMR applications of hexaaza macrocyclic complexes of lanthanides

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dc.contributor.advisor Name Illegible
dc.contributor.author DiSano, Mary
dc.date.accessioned 2010-02-03T22:15:53Z
dc.date.available 2010-02-03T22:15:53Z
dc.date.issued 1989-07
dc.identifier.uri http://hdl.handle.net/1850/11433
dc.description.abstract Samples of PrL(CH3C00)2Cl-nH20 ( L=2,7J3,1S,-tetremethyl- 3,6, 1 4, 1 7,23,24-hexaazatricycloi 1 7.3. 1 .18'12] tetracosa-1(23), 2, 6, 8, 10, 12(24), 13, 17, 19, 21-decaene) were tested as lanthanide shift reagents using 1-heptanol, diisopropyl amine and hexylamine as substrates. These tests were unsuccessful. Syntheses of similar compounds with nitrate, carbonate, picrate, and chloroacetate counteranions were attempted in our desire to prepare template complexes with displeceable counteranions. A successful lanthanide shift reagent has not yet been synthesized. en_US
dc.language.iso en_US en_US
dc.subject Lanthanides en_US
dc.subject Nuclear magnetic resonance imaging en_US
dc.subject.lcc QD77 .D574 1989
dc.subject.lcsh Lanthanide shift reagents--Testing en_US
dc.subject.lcsh Nuclear magnetic resonance spectroscopy en_US
dc.subject.lcsh Rare earth metal compounds en_US
dc.title Characterization and 1H-NMR applications of hexaaza macrocyclic complexes of lanthanides en_US
dc.type Thesis en_US
dc.description.college College of Science en_US
dc.description.department Department of Chemistry en_US

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