Process parameter modeling for nanocrystalline ceria based thin films prepared via aerosol jet printing

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dc.contributor.advisor Cormier, Denis
dc.contributor.advisor Esterman, Marcos Balasubramanian, Sundaresan 2012-10-23T18:45:23Z 2012-10-23T18:45:23Z 2012-08-24
dc.description.abstract Solid Oxide Fuel Cells (SOFCs) are becoming a popular choice for meeting energy requirements of the present day due to their high efficiency and reformation capabilities. SOFCs are made of ceramic oxides with well-defined physical and thermal properties enabling a high operating temperature range (600-800°C). Efficiency of a SOFC is typically well represented by its output voltage. Resistances across various compo- nents of the SOFC viz. anode, electrolyte and cathode diminish the maximum output voltage thus directly affecting the efficiency of the fuel cell. Each of the layers in a SOFC has generic as well as specific re- quirements warranting specialized fabrication processes. While such processes are many in number, they face limitations on size of the particles usable for the process, cost, ability to create graded porosity, thick- ness, etc. The main thrust of this work is the employment of a novel direct-write tool, namely the Optomec Aerosol Jet deposition system for fabricating the electrolyte layer of a SOFC that addresses some of the practical limitations of traditional SOFC fabrication techniques. While Optomec's Aerosol Jet deposition technique has been employed in several applications including printed electronics, a structured approach to identifying process parameters for printing materials was not found in literature. This work identifies and models process parameters significant to the deposition of nano- crystalline ceria with thickness of the deposited layer as response variable through design of experiments. Initial feasibility tests determined printability of the test ink and established a working range for the desired process parameters under investigation. A full factorial design with five factors and two levels was executed as the screening design. Three of five factors were determined as significant from the screening experiments. A regression equation was generated with the three significant terms from screening. Validation runs exe- cuted indicated lack of curvature within the design space for the significant parameters. Coefficients of terms from the regression equation were updated after regression analysis of a higher order design of experiments with three levels and the three significant parameters from screening. The updated regression equation provides a model with a reduced standard error and better fit of residuals as compared to the model from screening. A brief study on drying methods post-deposition and its impact on the quality of the printed film is also presented in this work. en_US
dc.language.iso en_US en_US
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dc.subject Aerosol jet deposition en_US
dc.subject Cerium dioxide en_US
dc.subject Direct write en_US
dc.subject Optomec en_US
dc.subject Process parameter modeling en_US
dc.subject SOFC en_US
dc.subject.lcc TK2933.S65 B35 2012
dc.subject.lcsh Solid oxide fuel cells--Design and construction en_US
dc.subject.lcsh Thin films--Design and construction en_US
dc.subject.lcsh Cerium oxides en_US
dc.title Process parameter modeling for nanocrystalline ceria based thin films prepared via aerosol jet printing en_US
dc.type Thesis en_US Kate Gleason College of Engineering en_US
dc.description.department Department of Industrial and Systems Engineering en_US

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