RhCl3-catalyzed hydroboration of alkenyl nitriles

Show full item record

Title: RhCl3-catalyzed hydroboration of alkenyl nitriles
Author: Buranov, A.; Morrill, Terence
Abstract: RhCl3-promoted hydroboration-oxidation reactions of representative alkenyl nitriles have been carried out. Carbanion of acetonitrile is formed from the carbon&unknown;carbon heterolytic bond breaking in allyl cyanide during hydroboration. An unexpected process-trimerization of carbanion of acetonitrile has lead to the formation of 4-amino-2,6-dimethylpyrimidine.
Record URI: http://hdl.handle.net/1850/2142
Publishers URL: http://dx.doi.org/10.1016/S0040-4039(03)01522-3
Date: 2003-08-11

Files in this item

Files Size Format View

An open access version of this file is not available. Check "Publisher URL" field for access

This item appears in the following Collection(s)

Show full item record

Search RIT DML


Advanced Search

Browse