RhCl3-catalyzed hydroboration of alkenyl nitriles

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Title: RhCl3-catalyzed hydroboration of alkenyl nitriles
Author: Buranov, A.; Morrill, Terence
Abstract: RhCl3-promoted hydroboration-oxidation reactions of representative alkenyl nitriles have been carried out. Carbanion of acetonitrile is formed from the carbon&unknown;carbon heterolytic bond breaking in allyl cyanide during hydroboration. An unexpected process-trimerization of carbanion of acetonitrile has lead to the formation of 4-amino-2,6-dimethylpyrimidine.
Record URI: http://hdl.handle.net/1850/2142
Publishers URL: http://dx.doi.org/10.1016/S0040-4039(03)01522-3
Date: 2003-08-11

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