A soluble linear Schiff-base coordination polymer containing eight-coordinate zirconium (IV)

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dc.contributor.author Archer, Ronald en_US
dc.contributor.author Illingsworth, Marvin en_US
dc.contributor.author Rau, Denise en_US
dc.contributor.author Hardiman, Christopher en_US
dc.date.accessioned 2006-07-19T19:39:56Z en_US
dc.date.available 2006-07-19T19:39:56Z en_US
dc.date.issued 1985-07 en_US
dc.identifier.citation Macromolecules 18N7 (1985) 1371-1376 en_US
dc.identifier.issn 1520-5835 en_US
dc.identifier.uri http://hdl.handle.net/1850/2169 en_US
dc.description.abstract The first soluble linear Schiff-base heavy-metal coordination polymer has been synthesized via the condensation of 1,2,4,5-tetraaminobenzene and tetrakis(salicylaldehydato)zirconium(IV) in dry dimethyl sulfoxide. The (N, N',N”,N”’-tetrasalicylidene-1,2,4,5-tetraaminobenzenato)zirconium(IV) polymer has a number-average molecular weight of up to 4.9 X 10^4 based on inherent viscosity, gel permeation chromatography, and elemental analysis. Spectral properties of this polymer indicate a structure analogous to the model compound bis(N,N’-disalicylidene-l,2-phenylenediamino)zirconium(IV). Thermal characterization of the polymer is also discussed. en_US
dc.format.extent 31371 bytes en_US
dc.format.mimetype application/pdf en_US
dc.language.iso en_US en_US
dc.publisher The American Chemical Society: Macromolecules en_US
dc.subject Chelation en_US
dc.subject Polymers en_US
dc.subject Synthesis en_US
dc.subject Zirconium en_US
dc.title A soluble linear Schiff-base coordination polymer containing eight-coordinate zirconium (IV) en_US
dc.type Abstract en_US
dc.identifier.url http://dx.doi.org/10.1021/ma00149a003

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