Application of the Reetz reagent, Dichlorodimethyltitanium, to develop sterically congested quaternary centers. The Synthesis of Herbertene

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Title: Application of the Reetz reagent, Dichlorodimethyltitanium, to develop sterically congested quaternary centers. The Synthesis of Herbertene
Author: Poon, Thomas; Mundy, Bradford; Favaloro, Frank; Goudreau, Christina; Collison, Christina
Abstract: A general protocol for conversion of a tetrasubstituted alkene to a highly methylated hydrocarbon is tested with a concise synthesis of the natural product, herbertene. The conversion: alkene --> 1,2-diol --> 1,2-dimethylated hydrocarbon should find application in a number of synthesis designs.
Description: This article may be accessed on one of the author's websites at: http://ochem.jsd.claremont.edu/pubs.dir/Synth_1998_p832(Poon).pdf
Record URI: http://hdl.handle.net/1850/7727
Date: 1998-06

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